The petite singer collected her award for Best Country Singer in a white gown with a revealing neckline.
Taylor (23) looked sleek and sophisticated in the sweeping floor length dress, with her hair loosely tied in to an up do. She completed the look with a pair of turquoise drop earrings.
While she stole the show in the style stakes, Taylor seemed subdued as she posed for photographs.
And One Direction were notably absent from the Awards Ceremony, despite being nominated in two separate categories.
Taylor and Harry dramatically split over the Christmas holidays. The pair had planned a romantic weekend away in The British Virgin Island, but things did not go to plan and Taylor flew back to the USA on her own after just three days on vacation.
Meanwhile, Harry visited Richard Branson's Necker Island home and was photographed larking about in a hot tub with bikini clad models.